Stereoregulation and Chiral Induction by Free Radical Polymerization
نویسندگان
چکیده
منابع مشابه
The Mechanism of Stereoregulation in Free-Radical Polymerization of Bulky Methacrylates
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Two types of photoinitiator are considered: (1) transition metal complexes (mainly carbonyls), (2) chelates of transition metals. In systems of type (1) the metal is in a low oxidation state and an organic halide is generally, but not always, present; on thc other hand, in (2) the metal is initially in a high oxidation state. Comparison between photoand thermal-initiation is made for each type....
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ژورنال
عنوان ژورنال: Kobunshi
سال: 1997
ISSN: 0454-1138,2185-9825
DOI: 10.1295/kobunshi.46.81